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     33     <h1>
     34      Drugs we can’t get: S1
     35     </h1>
     36     <p>
     37      <time id="post-date">2024-03-29</time>
     38     </p>
     39     <p id="post-excerpt">
     40      There are a number of interesting drugs used in the global market that,
     41     for one reason or another, do not have FDA approval and are therefore inaccessible
     42     in the US, at least outside of clinical trials. S1 is one of them: a better capecitabine.
     43     </p>
     44     <h2>
     45      What is S1?
     46     </h2>
     47     <p>
     48      S1 is the muy sexy common name of a drug manufactured by Taiho
     49 Pharmaceutical in Japan. (It did get a brand name a few years after it
     50 went to market: “Teysuno”).
     51     </p>
     52     <p>
     53      It is a combination of three drugs, all in a pill.
     54     </p>
     55     <p>
     56      The first is a prodrug, called tegafur or ftorafur (“FT” in many
     57 papers), that converts to 5-fluorouracil (5-FU) in the body.
     58 Capecitabine, the only oral 5-FU agent we use in the US, is also a 5-FU
     59 prodrug.
     60     </p>
     61     <p>
     62      The second is gimeracil, a drug that inhibits the enzyme
     63 dyhydropyrimidine dehydrogenase (DPD). This reduces tegafur breakdown in
     64 the GI tract, which allows it to make its way into the bloodstream.
     65 (Patients with inherent DPD deficiency cannot break down drugs in this
     66 family once they make it into the bloodstream, leading to potentially
     67 lethal side effects from 5-FU and it’s cousins - gimeracil is only
     68 creating a local DPD deficiency in the gut. Brilliant.).
     69     </p>
     70     <p>
     71      The third is oteracil, which prevents 5-FU activation in the GI
     72 tract, reducing off-target local adverse effects (capecitabine has
     73 horrible GI side effects in many patients). Also brilliant.
     74     </p>
     75     <p>
     76      <img src="/images/s1-is.png" alt="The FU drugs, including S1">
     77     </p>
     78     <p>
     79      This is a very rationally conceived drug. Using a prodrug with a
     80 companion that lets it survive long enough to be absorbed lets us use an
     81 oral formulation. Oral is so much more convenient than a pump the
     82 patient has to wear for a couple of days (and which sometimes
     83 malfunctions in strange ways). In capecitabine we already have an oral
     84 5-FU agent that works. However, many of the adverse effects of
     85 capecitabine are local to the GI tract, leading to dose reductions or
     86 drug switch in many cases, so combining something like capecitabine with
     87 something that reduces badness in this location also makes a lot of
     88 sense.
     89     </p>
     90     <p>
     91      This rationality bears out in clinical practice as well (this is not
     92 always the case - a popular saying amongst clinical trialists is “the
     93 road to hell is paved with biological plausibility.” The majority of
     94 ideas that work out well in a petri dish or animal model do not work out
     95 at all when we try them in humans. Hence clinical trials.). Trial after
     96 trial have established S1 as the standard of care in many relevant
     97 regimens in Asia, pretty much any situation where we would use
     98 infusional 5-FU or capecitabine in the US. (I’m sure there’s nuance
     99 here, but it appears generally true.) S1 works well, is easier to give,
    100 and is better tolerated.
    101     </p>
    102     <h2>
    103      So why don’t we have it in the US?
    104     </h2>
    105     <p>
    106      Good. Question.
    107     </p>
    108     <p>
    109      It’s not that it has been completely ignored by researchers in the
    110 West, as you’ll see. The Europeans can get it. And I’m sure Taiho would
    111 love to expand their market to the US.
    112     </p>
    113     <p>
    114      Truthfully, I can’t say I know all the reasons. These things are
    115 complex and the FDA’s reasons are not always readily apparent or written
    116 clearly (though they often are - I have equally strong respect and
    117 disdain for that particular agency, but the trend in my feeling is
    118 toward respect. I used to feel only disdain. The more I learn what and
    119 how they do All The Things, the more I see a bunch of humans really
    120 trying to do their best, rationally to the extent possible, in difficult
    121 situations, with many conflicting interested parties).
    122     </p>
    123     <p>
    124      The clearest reason that S1 is a Big Deal in Asia but unknown here is
    125 a difference in the prevalence of certain versions of enzymes that
    126 convert the tegafur to 5-FU.
    127     </p>
    128     <p>
    129      <em>Aside: I’m going to use the terribly imprecise terms “Asian” and
    130 “Westerner.” The studies in this area use the terms “Asian” and
    131 “Caucasian,” which is worse, as in, “even more wrong than the
    132 alternative I chose.” There is huge genetic and biologic variability
    133 within and across the places we call “Asia” and “The West,” and, if
    134 humans do anything, humans migrate. This biped was made for walkin’, and
    135 that’s just what it do. Don’t take these terms too seriously.</em>
    136     </p>
    137     <p>
    138      Folks from Asian countries tend to have a set of CYP2A6 polymorphisms
    139 that lead to much slower conversion of this particular drug, or, more
    140 appropriately said (Taiho is a Japanese company, after all), Westerners
    141 tend to have a CYP2A6 reality that makes them convert tegafur too damn
    142 fast. Dose-finding studies correspond well with the known differences in
    143 enzymes: the recommended daily dose in Asia is 40mg/m2 twice a day,
    144 whereas the Western dose is 30mg/m2 twice a day.
    145     </p>
    146     <p>
    147      There are other findings from the dosing studies that don’t precisely
    148 line up with differences in processing after absorption. The most severe
    149 toxicity in Asian populations is bone marrow suppression, whereas it is
    150 GI toxicity in Western populations. I don’t know why the oteracil
    151 doesn’t pull its weight in the guts of Westerners. Then again, it might
    152 be entirely unrelated to oteracil, I have no idea.
    153     </p>
    154     <h2>
    155      The Dutch, as usual, are leading the way
    156     </h2>
    157     <p>
    158      The most interesting study to-date using S1 in Westerners was done in
    159 the Netherlands and published as the “<a href="https://doi.org/10.1093/annonc/mdx122">SALTO Study</a>.”
    160     </p>
    161     <p>
    162      (S1 has approvals in Europe, though for a much shorter list of
    163 indications compared with Japan and China, so folks governed by the EMA
    164 can get it and play around, whereas there is no provision at all for
    165 getting it in the US outside of clinical trial - it has orphan
    166 designation but is not approved for anything)
    167     </p>
    168     <p>
    169      They looked at 161 patients who qualified for 5-FU-based monotherapy
    170 for metastatic colorectal cancer. Combination drug therapy is the
    171 standard of care frontline therapy in the metastatic setting, but
    172 monotherapy is a reasonable option for older and more frail patients,
    173 which is who this trial enrolled. They were randomized to S1 vs
    174 capecitabine, and compared efficacy as well as rates of adverse effects.
    175 Efficacy was comparable, and most adverse effects were also comparable,
    176 with the notable exception of hand-foot syndrome. The rates of this were
    177 45% in the S1 group, vs 73% in the capecitabine group. They were also
    178 better able to maintain dose intensity in the S1 group, which is a good
    179 surrogate for the <em>je ne sais quoi</em> of all the little things that
    180 being on therapy does to a person but aren’t fully captured in the other
    181 metrics. Though hand-foot syndrome is not a lethal problem, it can be a
    182 huge quality-of-life problem, particularly when the point of therapy is
    183 palliative in the first place.
    184     </p>
    185     <p>
    186      The same group also published a <a href="https://doi.org/10.1080/0284186X.2016.1278459">retrospective</a>
    187 on 52 patients who had hand-foot syndrome on capecitabine and were
    188 switched to S1, which they then tolerated beautifully. The graph below
    189 is from this paper. “Before” is on the left, and “after” is on the
    190 right. The difference is stark.
    191     </p>
    192     <p>
    193      <img src="/images/s1-cape-hfs.jpg" alt="HFS improves significantly after switching from capecitabine to S1">
    194     </p>
    195     <h2>
    196      Why I’d love to have S1 in the US
    197     </h2>
    198     <p>
    199      One tough part of my job is telling somebody who wants to continue
    200 therapy but isn’t tolerating the “easiest” form of therapy, even after
    201 dose reduction and maximizing supportive care, that their only options
    202 are to continue to push forward with the poorly tolerated therapy (to a
    203 degree - I’m not afraid to say no and refuse to prescribe if I feel like
    204 I’m hurting someone), or stop cancer-directed therapy altogether. I love
    205 hospice and the services it provides, and many patients are relieved to
    206 make this move, but a significant portion are not. Having another option
    207 in the armamentarium, something else to try for the patient who wants to
    208 try something, especially in such a commonly used class of drugs, would
    209 be great. S1 has clear benefit for patients who have an indication for
    210 5-FU-based therapy but have developed significant hand-foot syndrome,
    211 and I would use it in this situation if I had it on formulary.
    212     </p>
    213     <p>
    214      Also, though I practice in “the West,” not everyone here hails from
    215 the Caucasus
    216     </p>
    217     <p>
    218      <em>“Harumph,” he roared, suddenly on his feet and staring down at
    219 me, his tweed’s elbow patches straining as he assumed the pose of a
    220 portly academic Superman, “most Caucasians do not, in fact, hail from
    221 the Caucasus. Very few do. That was proto-eugenic Neo-Platonic foolery.
    222 If you use the term Caucasian, you have to accept the fallacious
    223 philosophy upon which it was built, and you are equally obligated to
    224 accept the terms from which it is inextricable, namely ‘Caucasoid,’
    225 ‘Mongoloid,’ ‘Negroid.’ Good sir, I do not believe this was your purpose
    226 nor desire. If you must use an imprecise term, at least let it be one of
    227 the cardinal directions, which are not unladen but are not actively
    228 destructive of scientific and societal progress, good sense, morality,
    229 and decency.” The final word was given in a whisper.</em>
    230     </p>
    231     <p>
    232      so having S1 as an up-front option for folks of Asian ancestry would
    233 be nice - it’s a clearly better drug in Asian countries, and I doubt it
    234 was the ground underfoot that made the difference.
    235     </p>
    236     <p>
    237      An idea related to this, with perhaps more biological justification
    238 than a nebulous definition of ancestry, would be to deploy CYP2A6
    239 screening of some sort to select folks who may most benefit from S1
    240 rather than capecitabine.
    241     </p>
    242     <p>
    243      This could be done in several ways, all of which have precedence in
    244 other types of screening and at some centers. Ideally you’d do trials to
    245 determine if any of these actually pan out (see above, on the path to
    246 hell). They’re all extrapolations.
    247     </p>
    248     <p>
    249      One option would be to screen all patients with known Asian ancestry,
    250 as is done in some centers for various indications (e.g. GPD deficiency
    251 screening for patients of African descent prior to starting potentially
    252 problematic drugs).
    253     </p>
    254     <p>
    255      Another would be to screen only those who have had dose-limiting GI
    256 intolerance to capecitabine, to make an argument that perhaps they would
    257 tolerate S1 better. (Though, in reality, if S1 was suddenly available
    258 and someone’s GI adverse effects were particularly horrendous on
    259 capecitabine, I’d probably talk with the patient about it and try it if
    260 they want, rather than what I might normally do, which would be to try
    261 infusional 5-FU or a drug from a different class, depending on the
    262 specifics of the situation. I think an empiric approach would be
    263 appropriate, as it wouldn’t require fancy testing which may or may not
    264 actually be predictive, and is what we do most of the time with other
    265 cognate drugs, even if they have class-effect toxicities - some folks
    266 just tolerate Drug A better than Drug B).
    267     </p>
    268     <p>
    269      A third option would be to screen everyone to try and find folks with
    270 compatible CYP2A6 to select for up-front S1. This is expensive. Only
    271 fancy places do population-wide pharmacogenomics (etc.) in practice, and
    272 there are deep debates about how much good this actually does. But hey,
    273 cool if you can get it, especially if you have data to back it up, but
    274 even then make you’d have to make sure you don’t take it without a grain
    275 or six of salt.
    276     </p>
    277     <p>
    278      As it is, even if I wanted to test out some of these ideas, or see if
    279 the Dutch prospective study replicates, I’d have to go through an insane
    280 approval process, and it would be expensive and time consuming. If the
    281 drug was approved and available, studies like the Dutch retrospective
    282 become almost trivially easy.
    283     </p>
    284     <p>
    285      One day. Maybe when the Big Boss of the FDA starts reading my blog
    286 and sends me a golden goose for my genius, along with a Christmas basket
    287 full of S1 and Cadbury. (That’s how it works, right?)
    288     </p>
    289     <h2>
    290      Until next time
    291     </h2>
    292     <p>
    293      This kind of thing is one of my favorites, a thoroughly enjoyable
    294 line of inquiry - what drugs are out there that I can’t get? What
    295 inspiration is there to be had from the practice patterns of other
    296 countries? Would those drugs and patterns work here - why or why
    297 not?
    298     </p>
    299     <p>
    300      It pairs nicely with my obsession with the histories of therapies for
    301 cancers. Love me a critical genealogy,* love me some heteroglossia and
    302 unfinalizability. Butler and Bakhtin ftw.
    303     </p>
    304     <hr>
    305     <p>
    306      * I idly wondered if there had been much movement on that term, which
    307 I got at least thirdhand from Judith Butler, and it looks like there’s
    308 going to be a cool book coming out in the next year or two: <a href="https://absolute-disruption.com/a-genealogy-of-genealogy/">A
    309 Genealogy of Genealogy</a>
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